Saturday, October 5, 2019
Poverty reduction in Brazil Essay Example | Topics and Well Written Essays - 2750 words
Poverty reduction in Brazil - Essay Example It is essential to adopt development strategy in order to achieve global prosperity, freedom, dignity, peace and equity along with sustaining progress already achieved. In order to carry out the study Bolsa Familia program, an initiative to combat poverty has been selected as the case. This case has been chosen for the further study as it is the major social program in the Social Protection System in Brazil. Moreover, Brazil has been selected as the country in concern for the study because Brazil by the end of the first decade of 21st century has emerged as one of the rapidly growing economies in the world. Moreover, Brazil has over the years engaged in conducting researches on poverty and inequality, thus there has been certain prominent changes witnessed by the country in the last decade that have drawn significant attention (Soares, Ribas and Osorio, ââ¬Å"Evaluating the Impact of Brazilââ¬â¢s Bolsa Familia: Cash Transfer Programs in Comparative Perspective â⬠). (ii) THES IS STATEMENT The local adoption of the Bolsa Familia program failed to promote the desired outcome. ... offers monthly transfer to poor families with children to extent of 15 years of age and/or pregnant woman as well as the program provides monthly transfer to extremely poor households irrespective of their composition. The Bolsa Familia program was launched on October 2003 by the government of President Lula da Silva under the Provisory Rule n.132 which was transformed in the law n. 10.836 in January 2004. The program is primarily a unified form of four major programs including Bolsa Escola, related with minimum income grant for primary education; Fome Zero and Bolsa Alimentacao, two major income subsidies associated with food security; and Vale Gas, a grant to help poor families buy cooking gas. The primary reason behind the implementation of the program was to achieve the objectives towards effectively combating hunger, poverty and inequalities through monetary transfer related with meeting the basic needs of household comprising health, education, food security and social aid. The program also aimed at promoting social inclusion for emancipation of the beneficiary household by assisting them to overcome vulnerable situations in which they are living (Soares, Ribas and Osorio, ââ¬Å"Evaluating the Impact of Brazilââ¬â¢s Bolsa Familia: Cash Transfer Programmes in Comparative Perspectiveâ⬠). The program is implemented in a decentralized manner in almost all the Brazilian Municipalities. It implements unverified method of testing that is conducted at the municipal level to select its beneficiaries. The program is firmly directed towards poor and indigent families who have per-capita income R$ 60 (US$ 33) and R$120 (US$66) (Souza, ââ¬Å"Poverty, Inequality and Social Policies In Brazil, 1995-2009â⬠). Correspondingly, those households with per-capita income of R$ 60 (US$ 33)
Friday, October 4, 2019
The New Testament in the Modern Church Essay Example | Topics and Well Written Essays - 5500 words
The New Testament in the Modern Church - Essay Example t times and contexts have approached the subject from many different angles but they all have the same aim of reflecting on the subject systematically. Christology aims to ââ¬Å"clarify the essential truths about him, it investigates his person and being and workâ⬠. (Oââ¬â¢Collins, 1994, p. 1), It is accepted by all that humans can never fully comprehend the mystery of God, but equally it has always been a key mission of the Church to study, and to teach key elements of the faith in a way which is at least partially evident to believers, and as far as possible relevant to each successive historical period and social context. Johnsonââ¬â¢s work is a good example of a contemporary theologianââ¬â¢s earnest attempts to get to grips with major issues like oppression of the poor and gender inequality, showing how and where the Church could and should evolve its mission to deal with these difficult challenges in the modern world. She identifies Christology as a starting poin t for discussion of these themes, arguing that hidden aspects of his being should be brought forward and that this process will prove especially relevant to the modern world. This paper will explore the strategies of interpretation that Johnson uses to present Jesus as ââ¬Å"Sophiaââ¬â¢s child, who communicates her gracious goodness by befriending the outcast, who communicates her prophetic message, and who proves her right or justifies her though he is severely criticized by others.â⬠(Fox, 2001, p. 127) It will look first at Johnsonââ¬â¢s starting point for this line of study, and then her use of Jewish traditions and Hellenistic influences, followed by her use of Patristic authorities through the ages. Finally Johnsonââ¬â¢s use of modern social sciences will be outlined, including historical and and socio-political techniques so that a full picture of her methods of interpretation can be gained, as well as an appreciation of how effective she is in sustaining these claims about Jesus. Elizabeth A. Johnson is
Thursday, October 3, 2019
Formal Analysis Essay Example for Free
Formal Analysis Essay ââ¬Å"My spirit takes journey, my spirit takes flight, could not have risen otherwise I am not running I am choosing. â⬠Alike is an intelligent and poetically talented 17 year old girl. On the surface, Dee Reesââ¬â¢s Pariah (2011), is the coming of age story of African-American lesbian, Alike. Growing up in a traditional household that is sexually repressed and a society that is hateful towards her for being homosexual she finds solace in poetry and academics. Through her plight, the film intelligently layers the dark themes associated with the struggles of a gay teenager growing up in the inner city- gender, sexuality, family relations, hate, religion, ignorance, etc. But the film is very hopeful in that it contrasts the dark themes with pleasant moments of optimism. I am analyzing one of the final scenes in the Dee Reesââ¬â¢s Pariah (2011). The scene [@ 01:15:11] where Alike is reconciling with Arthur, her father, on the rooftop of Lauraââ¬â¢s building. The rooftop scene encompasses the beauty of the morals of the narrative really well and at the same time contrasts the dark themes of the film in a manner that compliments the overall aesthetic of the production. The sceneââ¬â¢s Mise en Scene sets the tone for the conclusion of the narrative. The scene takes place on the rooftop of Lauras apartment building overlooking the sun setting over Brooklyn. Throughout the film we see Alike deep in thought several times; on the bus, in school, at the club- in all these circumstances the film utilizes dark, incandescent lighting and shadows to extenuate the tone of the emotions and events Alike is reflecting on. In this scene however the lighting comes from the bright, vibrant yellow-orange sunset. The film uses this in order to help visualize an appreciation of Alikeââ¬â¢s silver lining; almost as if to say that Alike seeââ¬â¢s the art and the beauty that came of her pain and suffering- this is expressed in the poem she reads against the montage of her leaving for California. Alikeââ¬â¢s outfit shows a more developed sense of style. This expresses to the audience that she has grown and maturated from the sequence of events that have taken place in the narrative. The social blocking of the conversation between Alike and Arthur brings Arthur down to a more human level. Although Arthur is angled slightly above Alike to maintain his domineering male complex, this is the first time in the film we see him venerable. Alike and Arthur face the opposite direction on an equal plane, this is supposed to demonstrate naturalistic interaction between the two as well as give a sense of the subjective perspective of the film. The cinematography in this scene is utilized to expresses the subjective point of view of Alike. The scene starts with a close up shot of Alike followed by a hand held long shot overlooking the sky Arthur and Laura entering. Shift in focus in depth of field demonstrates the importances of Alikeââ¬â¢s line ââ¬Å"Iââ¬â¢m not running, Iââ¬â¢m choosing,â⬠and Arthurââ¬â¢s reaction to it. We see that Arthur is man enough to accept his daughter for who she is and that he is not going to try to get her to run away from who she is, unlike his wife. The color balances of the yellow/orange spectrum is displayed in an aesthetically pleasing manner to help provide a strong sense of optimism, which is also complimented by the background noise of the wind and birds. The scenes in which Nina and Alike are bonding is a very optimistic time for Alike as well. And in those scenes the yellow/orange color spectrum is used to illustrate this but in a much darker tone. The reason for the darker tone being is that Alikeââ¬â¢s optimism was eventually destroyed after Nina tells her sheââ¬â¢s ââ¬Å"not really gay. â⬠Therefore, in using brighter tones in the rooftop scene, we get more of a sense of closure as an audience. The rooftop scene encompasses the beauty layered in within the dark ominous narrative of Pariah. The film is very aesthetically pleasing and has many layers to it. It does not follow a formulaic structure like most ââ¬Å"coming of ageâ⬠films do but instead uses poetry and pays attention to metaphoric details in order to tell Alikeââ¬â¢s story. Alikeââ¬â¢s growth from the confusion of her sexuality and identity is illustrated eloquently though the use of light, blocking, depth of field, and audio.
Vinegar as a Rust Remover | Experiment
Vinegar as a Rust Remover | Experiment Abstract Despite the vast research regarding rusting, still many people do not recognize the harmful effect it can to environment and to take precaution measure to avoid or prevent rusting. Results of study show U.S. had to spend total $276 billion, approximately 3.1% of the nations Gross Domestic Product (GDP) for corrosion direct cost. Therefore, these study is to find optional of artificial way to remove rusting from any other metal. For my research, I choose vinegar as a substance that has the potential to remove the rust stain from metal due to presence of acid in its content. Vinegar is easy to be obtained and usually use as households. I choose three different types of vinegar brands and analyzed its percentage by mass of acetic acid using acid-base titration technique. Then, I test the strength of each vinegar on rate of removing rust on rusted iron nail by removing the rust form. After that, I compare which vinegar has the highest rate of removing rust compared to its percentage by mass of acetic acid. As the result, I found out that different type of vinegar has different percentage by mass of acetic acid. But my experiment shows that, the higher percentage of acetic mass in the vinegar content, does not always lead to high rate of rust stain removal. These maybe due to my limitation of the research because I assumed that only acetic acid in vinegar reacts with the iron(III) oxide. Still, my research able to prove that vinegar can act as a potential rust stain remover but in low degree because acetic acid is weak acid. My research could help and provide people an easy way to remove rust from their accessories as vinegar could be easily obtained. 1. Introduction Vinegar can be define as a sour liquid obtained by result through acetic fermentation of dilute alcoholic liquids and used as a condiment or preservative. Aside from utilized widely, vinegar also can accommodate more than one purpose which usually used to enhance food taste. Vinegar is made through two stage of biological processes. These distinct process resulted from the action of innocuous microorganisms. In these process, yeast and Acetobacter is used to convert sugars (carbohydrates) into acetic acid. The first stage of process is called alcoholic fermentation. It occurs when yeasts convert natural sugars to alcohol under controlled conditions. In the second stage of process, Acetobacter which is a group of bacteria, changes the alcohol resulted from alcoholic fermentation to acid. This is the acid fermentation that forms vinegar. Since vinegar can be made from anything with sugar, there are probably too many variants to count made in countries throughout the world.[1](Kellen, 2 005, Vinegar Institute Site) Rust is define as the red or orange coating that forms on the surface of iron when exposed to air and moisture surroundings, consisting mass of ferric hydroxide. These ferric oxide is formed through oxidation. Rust forms due to the reaction of oxygen dissolved in dihydrogen monoxide(water) with iron. Rust also can be known or called as corrosion of metal.[2] (Holleman, Wiberg, 2001 Inorganic Chemistry Academic Press: San Diego) Rust is a general term to describe several different oxides that formed when an iron undergo corrosion. Some of the oxides are Fe(OH)2, Fe(OH)3, FeO(OH), and Fe2O3.H2O. The prevalent rust that can be found is a reddish-brown, Fe2O3.H2O. The oxygen in the air dissolve in water and promote the rust to start to compose. The rust also can be determine as an electrochemical process. The process of exchange of electrons (electricity) is conducted by chemical reactions in part of the electrical circuit. The surface of metal that exposed to electrolyte will undergo series of chemical reactions. Oxidation reactions (corrosion) occur at the surface of the anode while reduction reactions occur at the surface of the cathode.[3] (Jones, Denny (1996)Ãâà Principles and Prevention of Corrosion.) By observation, we could descried that rust occurs very easily because the presence of air and water or wet condition virtually presence anywhere. We could see around ourselves rusting is occur greatly. Rust changes steel into a different material, one that is impuissant or weaker than the original steel. Rusting is a immensely colossal problembecause so many things people use every day are made out of steel, like cars, bicycles, trucks, bridges, roofs, holding tanks, machinery, nuts, and bolts. When these objects are unprotected and exposed to water, they rust, and this damage can costs a lot of money. Rust also dangerous to human because a rusting iron nail can cause health issue such as tetanus if the iron nail pierce to human skin. Yet steel perpetuates to be widely used because it has an excellent strength-to-weight ratio. Also known as the best of all the common building materials. In addition, it is non-flammable, resistant to mold and termites, does not expand or contract und er temperature changes, and can be made with a consistent quality.[4] (Miller, L. (2003, July 31).Ãâà Corrosion). Therefore, we must take alert and precaution about rusting of these iron metal. The topic that be investigated in this extended essay is about rusting or corrosion and the way to prevent rust. Thus, my research question is to analyse the percentage by mass of acetic acid in different type of vinegar brands by using titration method and to investigate the potential of vinegar as rust stain remover. Therefore, my extended essay required two experimental procedures. My hypothesis for first experiment is that different types of vinegars have different percentage by mass of acetic acid. If the result of experiment one parallel with my hypothesis, second experiment could be carried out which is to investigate the potential of vinegar as rust stain remover. My hypothesis for second experiment is that the higher the percentage by mass of acetic acid in vinegar, the more efficient the vinegar to act as rust stain remover. The significant of my research is to investigate a cheapest and easiest way to remove rust. In this research, I choose vinegar as the potential method to remove stain rust because vinegar contain acetic acid . Vinegar could be easily found and present almost in every living house. Because acid is corrosive, it occur to me that the acid could corrode the rust stain from metal. To test the validity of my statement, a research and experimental procedure is carried out to justify the validity of my research question. The chosen area of study is rusting since my experiment focus more on rusting. These experiments included several methods such as acid base titration. Vinegar is acidic. Therefore, it will be titrated with base solutions, sodium hydroxide. The titration method is carried out to find the volume of base needed to neutralize the acid solution of vinegar. These method is essential for the experiment to find the percentage by mass of acetic acid in vinegar. Second method is rusting of iron nail. I could not choose any random iron nail to conduct my experiment because the result will not be accurate and precise as they could have different degree of rusting. Therefore, I buy iron nails that not rusted yet and undergo experimental procedure for the iron nails to rust under constant condition. These method needed to carry out so that the iron nails undergo rusting in constant activity. Then, the iron nails could be tested with the vinegar. In my experiment, I used some instrument from the chemistry laboratory. The instruments I used is pH meter. The pH meter is used to find the pH of different type of vinegar. I also use burette which is necessary for the titration method. The burette is used to find the volume of base needed to neutralise the acidic solution. I also used electronic balance to weigh the iron nails initial mass before in undergo rusting and the final mass after the iron nails undergo rusting. Stopwatch is used to record the time taken for the acid to remove the rust stain. *Due to some error, all the pictures for the experiment have loss. 2. Methodology: 2.1 Variables and method of controlling variables Variable type:à Independent Variable:à Different type of vinegar brands Method of controlling:à By using vinegar of different brands for the experiment. Variable type:à Dependent Variable:à Volume of sodium hydroxide needed to neutralize acid solution Method of controlling:à By measured the volume of sodium hydroxide needed to neutralize acid solution using burette. Variable type:à Controlled Variable:à Volume of vinegar used Method of controlling:à Fixed the amount of vinegar is used for the experiment which is 2.0 ml. Variable:à temperature Method of controlling:à The experiment is conducted in same room Variable:à Volume of distilled water added Method of controlling:à Fixed the amount of volume distilled water added in the vinegar. Add phenolphthalein Method of controlling:à By adding 3 drops phenolphthalein to every vinegar solution in conical flask during experiment. Variable:à Concentration of sodium hydroxide Method of controlling:à By fixed the concentration of sodium hydroxide used which is 1.0 M. Table 1 : Variables for experiment to determine the percentage by mass of acetic acid in vinegars Variable type Variable Method of controlling Independent Type of vinegar used By using vinegar of different brands for the experiment. Dependent Time taken to remove the rust stain By recorded the time taken for different type of vinegars to remove the rust stain on the iron nail using stop watch. Controlled Type of metal By using the same metal throughout the experiment which is iron nail. Temperature The experiment is conducted in same room Using same electronic balance By using the same electronic balance to weigh the mass of iron nail. Time for iron to rust Fixed the time for the iron to rust which is 7 days or i week Using same stopwatch By fixed the type of stopwatch used to record the time taken. Table 2 : Variables for experiment to determine the time taken for the vinegars to remove rust 2.2 Methodology for neutralisation process To find the percentage by of acetic acid in different types of vinegar brands, a neutralisation process follow the standard procedure is carries out. First , the apparatus is set up . The burette is clamped on the retort stand. Then, 2.0 ml of vinegar is measured using measuring cylinder. An empty conical flask is weighed. Then 2.0 ml vinegar which is Earth Brand is poured in the conical flask. The conical flask is weighed again. This procedure has to be carried out to find the mass of 2.0 ml of vinegar assumed that different vinegars has different density. After that, 48.0 ml of distilled water is measured using measuring cylinder. Then, the distilled water is mixed with the vinegar in the conical flask. This procedure has to be carried out because vinegar is very concentrated so dilution process has to be done. The pH mater is used to find the pH value of vinegars. After mixed, the initial weight of vinegar with conical flask is measured using weighing balance. Then , sodium hydroxide is filled in the burette. The conical flask is placed under the burette. 3 drops of phenolphthalein is added into the diluted vinegar. The neutralisation process is started as soon the alkali is added into the conical flask. The sodium hydroxide is assumed to only react with the acetic acid presence in the vinegar. The conical flask is swirled gently. The initial colour for the acidic solution is colourless. As the acid solution undergo titration, the colour change from colourless to pale pink colour. The end of titration is indicated when the mixture remains in pale pink colour. The titration process is stopped. The volume of sodium hydroxide needed to neutralise 2.0 ml of vinegar is recorded and final weight of vinegar with conical flask is weighed. The experiment above is repeated twice to get the average reading of volume of sodium hydroxide needed to neutralise the acid solution. All the data is recorded in the table. The experiment procedure above is then repeated using different type of vinegar which is Yeos and Jalen. Burette, Ãâà ±0.05 cm3 Different vinegar brands (Jalen, Yeos, Earth Brand) Beaker, Ãâà ±0.5 Conical flask ,Ãâà ±0.5 Retort stand and clamp Pipette and ph meter Phenolphathalein Weighing balance , Ãâà ±0.0001 Sodium hydroxide (1.0 molar) Rod and distilled water 2.3 Methodology for rusting process and rust stain removal This experimental procedure is carried out because it is hard to determine the degree of rusting of any random metal. Therefore, I fixed the type of metal use which is iron nails and the time left for iron to rust which is approximately 7 day (1 week) . The materials is ready and apparatus needed is set up. The initial mass of each iron nail is weighed and the data is recorded. The 5 iron nails is marked such as iron nail A, iron nail B and consecutively by using a small piece of paper attached to each nail. Then , a mineral bottle is cut to get the bottom part of mineral bottle and form a cup like. Then, the cup is filled with small amount of tap water. All iron nails is dipped in the water and left to be exposed to air in the laboratory for seven days. After seven days , all iron nails are take out from the bottle. Then, each iron nail which already rusted now is weighed again to get mass of rust with the iron nail. The mass of rust formed on each iron nail is found by subtracted the final weight of iron nail with its initial weigh. Then, the average mass of rust formed is calculated. All the data of the experiment is recorded in a table. The experiment above is repeated twice. The process to remove rust stain is carried out. Vinegar is inserted into a transparent cup. The rusted iron nail is immersed into the cup contained vinegar. The reaction is observed. The time taken for the iron rust to be remove completely by the vinegar from the iron nail is recorded by using stopwatch. The same procedure done to all 5 iron nails . The average time taken needed to remove the rust is calculated. The data and result is tabulated. The experiment above is repeated using different type of vinegars. Apparatus and materials Burette, Ãâà ±0.05 cm3 Beaker, Ãâà ±0.5 Bottle cup Different vinegar brands (Jalen, Yeos, Earth Brand) Conical flask ,Ãâà ±0.5 Measuring cylinder, Ãâà ±0.05 Weighing balance , Ãâà ±0.0001 5 Iron nails Distilled water 3. Data collection and processing 3.1 Data collection and processing for experimentà Quantitative data Type of vinegar brand Weight of empty conical flask (g) Ãâà ±0.0001 Weight of 2.0 ml of vinegar with conical flask (g) Ãâà ±0.0001 Mass of vinegar Ãâà ±0.0002 (g) Earth Brand Qualitative data The initial colour of vinegar and sodium hydroxide is colourless. The colour of vinegar solution remains colourless even after phenolphthalein is added. When the mixture undergo titration process, the mixture remains colourless but when the end point of titration reach, the colour of mixture turns from colourless to pale pink. Equation for the neutralization process = CH3COOH (aq) + NaOH (aq) à ¢Ã¢â¬ ââ¬â¢ CH3COONa (aq) + H2O (l) Calculation of percentage by mass of acetic acid in vinegars. 1. Earth Brand Calculate number of moles for NaOH = MV 1000 (32.54 ml of NaOH solution added x 1.0 molar of NaOH) 1000 = 0.03254 moles of NaOH uncertainties =( 0.05/ 32.54) x 100% = 0.15 % CH3COOH (aq) + NaOH (aq) à ¢Ã¢â¬ ââ¬â¢ CH3COONa (aq) + H2O (l) From the equation , the acetic acid in vinegar reacts with sodium hydroxide in a 1:1 ratio. 1 mole of acetic acid reacts with 1 mole of sodium hydroxide to for 1 mole of sodium acetate and 1 mole of water. Thus, 0.03254 mole of acetic acid reacts with 0.03254 mole of sodium hydroxide to form 0.03254 mole of sodium acetate and 0.03254 mole of water. Calculate the amount of acetic acid in Earth Brand. Therefore, Molecular mass calculation: 12.0107 + 1.00794*3 + 12.0107 + 15.9994 + 15.9994 + 1.00794 = 60.05196 g/mol To find the mass of acetic acid in vinegar is given by the formula number of mole x molar mass of acetic acid Thus, 0.03254 moles x 60.05196 g/mol = 1.954 g of acetic acid Ãâà ± 0.15 % To calculate the percentage by mass of acetic acid in vinegar (Earth Brand): Mass of vinegar use= 2.2837 g uncertainties = (0.0001/2.2837) x 100% = 0.0044 % mass of acetic acid in vinegar = 1.9540 g The percentage by mass of acetic acid =(1.9540/2.2837 ) x 100 = 85.56 % uncertainties = 0.0044 + 0.15 = 0.1544 % Therefore, the percentage by mass of acetic acid in Earth Brand is = 85.56 % Ãâà ± 0.15 % The method of calculation of percentage by mass of acetic acid for other vinegars is same with the calculation above. Therefore, the result for the calculation is tabulated. Discussion The 2.0 volume for vinegar used needed to be weighed to find the mass of vinegar as I assumed the density for vinegar is different from density of water. From the result, it shows that different vinegars has different density, therefore different vinegars will have different mass of 2.00 volume used. I also assumed that during neutralisation process, the sodium hydroxide will only reacts with the acetic acid presence in the vinegar. Based on the result , it shows that different type of vinegar brands has different percentage by mass of acetic acid of vinegar of different brands. Jalen has the highest percentage by mass of acetic acid followed by Earth Brand and Yeos. These explained that why different vinegars have different ph value. Acetic acid is weak acid. The higher the percentage by mass of acetic acid, the lower the pH value of the vinegar. Hypothesis for experiment one is accepted. Different type of vinegar has different percentage of acetic acid of vinegar. Thus, experiment two can be conducted. 3.2 Data collection and processing for experiment 2 Quantitative data The iron nail pale brown in colour while the tap water and the vinegar is colourless. When the iron nail is left in the bottle cup, there is no immediate reaction occured. After several hours, a reddish brown substance start to appear around the iron nail. After several days more reddish brown substance deposited around the iron nail like coated it. When the iron is immersed in vinegar inside a cup bottle, bubble formed and the reddish brown substance fall off from the iron nail. The colour of vinegar turned slightly from colourless to pale reddish and the reddish substances settle at the bottom of the cup bottle. Later, it dissolve in the vinegar. 4. Processed result Discussion To put in a simple words, rusting is the corrosion of iron and readily occurs in the metal in the presence of water , oxygen and iron. The formation of a reddish brown substance like which appeared and adheres to the iron nail is called rust. Based on the research, it shows that vinegar could serve as one of the substance that can remove rust stain on metal due to the presence of acid. From the experiment , It clearly shows that different vinegar has different degree of removing the rust stain because due to different percentage by mass of acetic acid in the different type of vinegars. After rusting process occurs on the iron nail, the iron nail weighed more. These is because rustÃâà forms when iron metal is oxidized by oxygen in the presence of water . Iron oxide is another term for rust. Iron oxide as a molecule and consist of three elements which is of iron with oxygen and water. From the result obtained based on the experiment, it shows that the rust form is originally mass from the iron but the mass of oxygen and water comes from the atmosphere. When the rust form on the iron nail, the mass of iron rust increased by the mass of oxygen and water that combined with the iron. Therefore, iron nail weight more after rusting process occurs due to addition of these elements from atmosphere. In the presence of oxygen and water, Reduction half equation: 4e- + 2H2O(l) + O2(g) > 4OH-(aq) The tip or the head component of iron nail is easily oxidised. The crystal lattice of iron is distorted and the iron atoms will be facilely oxidised. Oxidation half equation: 2Fe(s) > 2Fe2+(aq) + 4e- Therefore the overall net equation for the chemical reaction is 2Fe(s) + 2H2O(l) + O2(g) > 2Fe2+(aq) + 4OH-(aq) The process continue. After that, the Fe2+ and OH- ions will move and diffuse through the water. When both ions meet they will react to produce precipitate which iron (II) hydroxide , Fe(OH)2 .These iron (II) hydroxide then will be further oxidise to iron (II) hydroxide, Fe(OH)3 and will be dehydrated to produce rust. Chemical equation for rusting process : 2Fe(s) + 2H2O(l) + O2(g) > 2Fe2+(aq) + 4OH-(aq) Fe2+(aq) + 2OH-(aq) > Fe(OH)2(s) Fe(OH)2(s) + O2 > Fe(OH)3(s) Fe(OH)3(s) dehydrates > Fe2O3.nH2O(s) or rust Therefore, the chemical formula for rust is Fe2O3.nH2O(s) [5] (Loh Wai Leng,Tan Yin Toon,Tan On Tin, 2011, oxidation and reduction) Acetic acid is a weak acid that presence in vinegar. Vinegar works well than other strong acid because the presence of weak acid. Therefore, it will less attack the iron nail itself. Strong acid will corrode both the rust stain and the iron nail. To prevent that, substance with weak acid is preferable. When the iron nail with rust is soaked into the vinegar containing acid, the rust on iron nail will dissolve and loosen. The crumbly hydrated iron oxide will form a soluble salt, in these reaction between acetic acid and iron(III) oxide, it will formed iron acetate. Equation of reaction between acetic acid and rust: 6CH3COOH(l) + Fe2O3 (s) > 2Fe(CH3COO)3 (s) + 3H2O (l) and ferric acetate, Fe(CH3COO)3 is water soluble. However, the hypothesis for my second experiment is rejected. Clearly from the experiment above, it shows there is no directly proportional relationship between percentage of mass of acetic acid in vinegar and rate of removing rust. Jalen has the highest percentage of mass of acetic acid followed by Earth Brand and Yeos but Earth Brand shows the highest rate of removing rust followed by Jalen and Yeos. There, my experiment has limitation which lead to these result. After the experiment, I accidentally left the iron nail that already washed with vinegar in the cup bottle. I found out that the rusting on iron nail occur more faster by the day. I concluded myself that acid actually can remove the rust stain from the nail but in the same time it also promote rusting. The surface of iron nail will clean after the rust stain is remove and let the iron nail exposed to acid. Somehow, acid will react on the surface of iron nail. Further research could be done to investigate the after effect of acid after removing the rust stain. 5. Conclusion This research show that each vinegar has it own percentage by mass of acetic acid in each and every different type of vinegar. From the experiment and calculation, it shows that the percentage by mass of acetic acid in vinegar brands of Earth Brand, yeos and Jalen accordingly is 85.56%, 83.68% and 92.20%. The difference of percentage by mass of acetic acid in vinegar resulted the difference in the vinegar taste and the pH value. The experiment shows that there is not much significant difference of percentage by mass of acetic acid in different type of vinegar brands. The vinegars used in the experiment is the product of Malaysia . Different result may show if I test of the products of other country. These difference of percentage of acetic acid in different type of vinegar, effect the result obtained in experiment two. The hypothesis for experiment one is accepted. These research also shows that vinegar could serve as a potentially rust stain remover but in low degree because acetic acid presence in vinegar is a weak acid. Still, it could be use safely because the acidic concentration is not harmful and vinegar is easy to obtain rather than any other applications. However , from the result obtain, it shows that the higher the percentage of acetic acid in vinegar, does not always cause higher rate of rust stain removal. Jalen has the highest percentage by mass of acetic acid in vinegar followed by Earth Brand and Yeos which is 92.20%, 85.56% and 83.68% respectively. But the experiment shows that the vinegar that has the highest degree of rust stain removal is Earth Brand followed by Jalen and Yeos which is 0.0049gs-1, 0.0044gs-1 and 0.0043gs-1 second respectively. Therefore I could conclude that , Earth Brand is a better rust stain remover Yeos and Jalen , but Jalen is better than yeos. Even though there is no not much significant difference, but it effected the overall result. Therefore, the hypothesis for the second experiment is not accepted. There is several reason why these result obtained. Maybe there is another substance that presence in the vinegar, react with the rust stain on iron nail which can affect the result because I assumed that the rust stain will only react with the acetic acid presence in vinegar. Further research could be conducted to explain and determine the problem. The other reason may cause due to limitation that will be discuss later. However ,these research able to prove that there is difference of percentage by mass of acetic acid in different type of vinegar and vinegar can act as a potentially rust stain remover . But due to weak acid presence in vinegar, vinegar could only remove rust stain that only form only on surface of metal . It cannot remove the rust that has been deeper into metal . Overall, I can conclude from the experiment that different vinegar has different percentage by mass of acetic acid and vinegar is a highly potential rust stain remover. 6. Evaluation Throughout the experiment there are several limitations that can affect the result of the experiment. During the titration process, The colour of acidic solution which is vinegar, will change from colourless to pale pink at the end of titration process. The perception of colour change will affect the result. It is hard to determine what the exact pale pink colour that need to be achieve. In order to overcome this problem, a controlled conical flask containing acid solution when end point of titration which colour is pale pink should be put beside the set up apparatus so that the person would know what exactly pale pink colour they need to reach. pH meter also can be used to fixed the pH value needed. Another problem that could effect the result is when weighing the weight of iron nail after the rust is formed. Rust that is formed for several days only appear on the surface of the iron nail. Therefore, when removing the iron nail to be weighed, the rust from the surface of iron nail could drop. Even a slight drop of rust from the iron nail, could cause the result obtained will not be accurate . Therefore, to overcome these problem, during the formation of rust, the iron nails should be left on the electronic balance. So, the iron nail does not have to be removed and rust will not fall off. The result obtained will be more precise. Another problem that could arise is when removing the rust from iron nail using vinegar. In these experiment, I assumed that, only acetic acid in vinegar will react with the rust on the iron nail. So that my hypothesis could be achieved. But it turn out my hypothesis is invalid. It could be that other substances presence in the vinegar, will react with the rust on the iron nail. After all, vinegar consist more than one substance. these problem can be overcome by doing some further research. Lastly, the after effect of the experiment. Acid can remove rust stain but the chemical reaction between acid and the surface of iron nail, can increase the rate of rusting of iron nail. Corrosion in acid solutions is much more rapid than in neutral solutions, and the latter is more rapid than in alkaline solutions.[6](Frank N. Neller,2004, Corrosion Facts). Therefore to solve the problem, after washed the iron nail to remove the rust, the iron nail need to place in boil water for a while. Therefore, no after chemical reaction will occur. Thus, rusting will not occur.
Wednesday, October 2, 2019
Delta Airlines :: essays research papers fc
While sitting in Atlantaââ¬â¢s Hartsfield International Airport, one cannot help but to notice and feel an overwhelming dominant presence of one particular airline. Delta as we know it today, traces its roots way back to 1924. Huff Daland Dusters was founded as the worldââ¬â¢s first aerial crop dusting organization. In 1928 the company became Delta Air Service, and the following year Delta carried its first passengers over a route stretching from Dallas, Texas to Jackson, Mississippi with stops in Shreveport and Monroe, Louisiana. In 1941, the company moved its headquarters from Monroe to Atlanta, Georgia. Although headquartered in Atlanta, Delta is a Delaware corporation (Delaware is the most ââ¬Å"pro-businessâ⬠state in the US). Delta Air Lines Inc. provides air transportation for passengers and freight throughout the United States and around the world. As of February 1, 2001, Delta (including its wholly owned subsidiaries, Atlantic Southeast Airlines, Inc. and Comair, Inc.) served 201 domestic cities in 45 states, the District of Columbia, Puerto Rico and the U.S. Virgin Islands, as well as 50 cities in 32 countries. With its domestic and international code share partners, Delta's route network covers 218 domestic cities in 48 states, and 131 cities in 58 countries. When analyzing Delta, you do not have to search very far before quite possibly one its strongest attribute rears its head. Based on calendar 2000 data, Delta is the largest U.S. airline in terms of aircraft departures and passengers enplaned, and third largest as measured by operating revenues and revenue passenger miles flown. Delta is the leading U.S. airline in the transatlantic, offering the most daily flight departures, serving the largest number of nonstop markets and carrying more passengers than any other U.S. airline. Delta Air Lines transports more passengers worldwide than any other airline. Through a vast worldwide route system Delta has flown over 117 million passengers, more than any other airline in the world. Delta mainline, domestic and international service, Delta Express, Delta Shuttle, Delta Connectionà ®, Delta Sky Team and Worldwide Partners operate 6,400 flights each day to over 450 cities in 98 countries. Not only is Delta a beast in the market it wields its power quite intelligently. Along with this momentous market share, Delta has enormous control over some of the nations key gateways. Delta controls 72 percent of the air traffic at Salt Lake Utah. This mid west city is a gateway to most of the key major cities on the pacific coast as well as mid west.
Tuesday, October 1, 2019
plotlear Parallel Plots of Shakespeares King Lear Essay examples --
The Parallel Plots of Shakespeare's King Lear à à à à à à à à Many works of literature contain parallel plots in which similar actions taken by various characters precipitate identical results.à Upon careful examination, it is evident that ââ¬Å"such plots exist in Shakespeare's play King Lear with the deaths of King Lear, Cordelia, Edmund, and Goneril, among othersâ⬠(Curry 17).à The betrayal of a commitment to an authority figure is the cause behind each of the above characters' death.à Likewise, the consistent loyalty of Kent, the Fool, and Edgar is rewarded when they outlive their traitorous peers. King Lear, who as a divine-right king derives his power from God, betrays God's will when he transfers his kingdom to his daughters, Reagan and Goneril.à When Lear states that his purpose in doing so is "To shake all cares and business from our age, / Conferring them on younger strengths while we / Unburdened crawl toward death." (Shakespeare 2) he declares his intention to delegate his power so that he is no longer bothered with great responsibilities.à In this self-serving act, Lear is unfaithful to God, whose wish it was for Lear to rule for a lifetime.à Later, God's wrath is apparent in Act III Scene II when Lear speaks to a tempest, a manifestation of God's anger at the strife within the kingdom, and tells it to "Rumble thy bellyful! Spit, fire! Spout rain! / Nor rain, wind, thunder, fire are my daughters" (Shakespeare 60).à à Evidently, upon seeing the tempest, Lear is aware that he made a mistake and betrayed God's trust.à In speaking to the tempest, he asks for God to correct the situation by causing Reagan and Goneril to fall from power.à As a result of his unfaithfulness to God, Lear dies of a broken heart in the end of ... ...the conclusion of the play. à à à à à à à à à à à As is by now apparent, there are a multitude of parallel plots within Shakespeare's play King Lear.à In each plot, a character's breach of loyalty condemned the character to certain death in the final scene of the play.à Several of the characters who exhibited treachery and later died were King Lear, Cordelia, Edmund, and Goneril.à Accordingly, Kent, the Fool, Edgar, and Albany all survived the play because they did not cast aside their loyalties. Works Cited and Consulted Bradley, A.C. Shakespearean Tragedy. Macmillan & Co., 1965 Curry, Walter. Studies of the Structure of Shakespeare. London: Mass Peterà Smith, 1968.à à Shakespeare, William. The Tragedy of King Lear.à Ed. Russell Fraser.à New York: Penguin, 1998. Webster, Margaret. Shakespeare Without Tears. Greenwich: Fawcett Publications, Inc., 1996.
International Humanitarian Law
INTERNATIONAL HUMANITARIAN LAW and THE IRAQ CRISIS SUSAN SOUX April 2003 International Humanitarian Law ? the RULES which seek, for humanitarian reasons, to limit the effects of armed conflict, protect people who are not, or are no longer taking part in the hostilities, and to restrict the methods and means of warfare employed IHL ââ¬Ëthe law of armed conflictsââ¬â¢ or or ââ¬Ëlaw of warââ¬â¢ â⬠¢ Geneva â⬠¢ Hague Geneva ââ¬Ëthe law of Geneva is designed to safeguard military personnel who are no longer taking part in the fighting and people not actively involved in hostilitiesââ¬â¢ Hors de combat â⬠¢ Civilians â⬠¢ Medical/religious personnel The Hague ââ¬Ëthe law of The Hague establishes the rights and obligations of belligerents in the conduct of military operations, and limits the means of harming the enemyââ¬â¢ International humanitarian law prohibits all means and methods of warfare which: â⬠¢ fail to discriminate â⬠¢ cause superfluo us injury or unnecessary suffering â⬠¢ cause severe or long-term damage to the environment. Other agreements prohibit the use of certain weapons and military tactics and protect certain categories of people and goods. ? he 1954 Convention for the Protection of Cultural Property in the Event of Armed Conflict, plus its two protocols; ? ? ? the 1972 Biological Weapons Convention; the 1980 Conventional Weapons Convention and its four protocols; the 1993 Chemical Weapons Convention; ? the 1997 Ottawa Convention on anti-personnel mines; ? the 2000 Optional Protocol to the Convention on the Rights of the Child on the involvement of children in armed conflict. Many provisions of international humanitarian law are now accepted as customary law ââ¬â that is, as general rules by which all States are bound. HENRI DUNANT ââ¬ËBATTLE OF SOLFERINOââ¬â¢ History â⬠¢ 1859 ââ¬â Battle of Solferino â⬠¢ 1863 ââ¬â ICRC â⬠¢ Geneva Conventions ââ¬â 1864 â⬠¢ Hague laws ââ¬â 1899/1907 â⬠¢ 1949 ââ¬âGeneva conventions â⬠¢ 1977 ââ¬â Additional Protocols Geneva Conventions 1949 Convention (I) for the Amelioration of the Condition of the Wounded and Sick in Armed Forces in the Field. Geneva, 12 August 1949. Convention (II) for the Amelioration of the Condition of Wounded, Sick and Shipwrecked Members of Armed Forces at Sea. Geneva, 12 August 1949. Convention (III) relative to the Treatment of Prisoners of War. Geneva, 12 August 1949. Convention (IV) relative to the Protection of Civilian Persons in Time of War. Geneva, 12 August 1949. Iraq ratified Geneva Conventions 1956 US ratified in 1955 Additional Protocols 1977 â⬠¢ Protocol Additional to the Geneva Conventions of 12 August 1949, and relating to the Protection of Victims of International Armed Conflicts (Protocol I), 8 June 1977. Protocol Additional to the Geneva Conventions of 12 August 1949, and relating to the Protection of Victims of Non-International Armed Conflicts (Protocol II), 8 June 1977. Neither Iraq nor the US have ratified the Protocols International Human Rights Law â⬠¢ Universal Declaration of Human Rights ââ¬â1948 â⬠¢ International Covenant on Social,Economic and cultural Right â⬠¢ International Covenant on Civil and Political Rights â⬠¦other conventions/covenantsâ⬠¦ â⬠¢ Convention on the Status of Re fugees ââ¬â 1951 â⬠¢ Guiding Principles on Internal Displacement 1998 International Tribunals â⬠¢ â⬠¢ â⬠¢ â⬠¢ â⬠¢ Nuremburg ICTY ââ¬â Hague ICTR ââ¬â Rwanda Sierra Leone International Criminal Court (Rome ââ¬â 1998/2002) â⬠¦ Universal Jurisdiction â⬠¦ ââ¬ËGenocideââ¬â¢ ââ¬ËWar Crimesââ¬â¢ ââ¬ËCrimes Against Humanityââ¬â¢ Current Issues â⬠¢ Allegations of indiscriminate bombing â⬠¢ Targeting under IHL â⬠¢ Ensuring Humanitarian Access â⬠¢ Status of Combatants, Civilians and Civilians Taking Up Arms â⬠¢ Suicide Attacks ââ¬â ââ¬ËPerfidyââ¬â¢ â⬠¢ Occupying Forces International Red Cross Protectors of the Geneva Conventions impartial, neutral and independent from any political objectiveââ¬â¢ â⬠¢ â⬠¢ â⬠¢ â⬠¢ â⬠¢ ââ¬ËRight to be presentââ¬â¢ when conflict breaks out Protect the lives and dignity of victims of war Monitors compliance with Geneva Conventions Visits POWââ¬â¢s Provides medical/humanitarian assistance IRAQ ICRC ââ¬â in battle areas â⬠¢ â⬠¢ â⬠¢ â⬠¢ Hospitals Water Powââ¬â¢s Tracing IFRC and Red Crescent Societies ââ¬â outside the battle â⬠¢ Refugee camps â⬠¢ Tracing â⬠¢ Humanitarian assistance International Delegates Water Systems Medical Assistance Family Tracing Refugee Camps Orthopaedic Centres Orthopaedic Centres Resources: â⬠¢ â⬠¢ â⬠¢ â⬠¢ â⬠¢ â⬠¢ www. icrc. org www. ifrc. org www. redcross. ca http://www. ihlresearch. org/iraq/ http://www. reliefweb. int/ocha_ol/civilians/ www. unhcr. ch ââ¬Å"As human beings, we cannot be neutral, or at least have no right to be, when other human beings are suffering. Each of usâ⬠¦ must do what he or she can to help those in need, even though it would be much safer and more comfortable to do nothing. â⬠ââ¬â Kofi Annan UN Secretary-General
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